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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Onkarappa, S.B. | - |
| dc.contributor.author | Dutta, Saikat | - |
| dc.date.accessioned | 2020-03-31T08:36:00Z | - |
| dc.date.available | 2020-03-31T08:36:00Z | - |
| dc.date.issued | 2019 | - |
| dc.identifier.citation | ChemistrySelect, 2019, Vol.4, 19, pp.5540-5543 | en_US |
| dc.identifier.uri | https://idr.nitk.ac.in/jspui/handle/123456789/11966 | - |
| dc.description.abstract | A series of 5-(alkoxymethyl)furfurals (AMFs) have been synthesized in excellent isolated yields (>90%) by reacting biomass-derived 5-(chloromethyl)furfural (CMF) or 5-(bromomethyl)furfural (BMF) with monohydric alkyl alcohols (methanol to 1-butanol) at slightly elevated temperatures (RT-50 C) and short reaction time (3 h). The modified work-up procedure minimizes side reactions while simplifying the isolation and purification of AMFs. Although higher primary alcohols like 1-pentanol and 1-hexanol and secondary alcohol like 2-propanol were found to be less reactive, use of N,N-diisopropylethylamine (DIPEA) as a base additive afforded AMFs in excellent yields within 6 h at 65 C using only slight excess of the alcohol (1.2 eq.) reagent. 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | en_US |
| dc.title | High-Yielding Synthesis of 5-(alkoxymethyl)furfurals from Biomass-Derived 5-(halomethyl)furfural (X=Cl, Br) | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | 1. Journal Articles | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 6 High-Yielding Synthesis.pdf | 843.29 kB | Adobe PDF |  View/Open |
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